1,3,6-Trihydroxy-7-methoxy-2,8-bis(3-methylbut-2-enyl)-9H-xanthen-9-one
نویسندگان
چکیده
The title compound (trivial name α-mangostin), C(24)H(26)O(6), isolated from Cratoxylum glaucum, is characterized by a xanthone skeleton of three fused six-membered rings and two 3-methyl-but-2-enyl side chains. The three rings in the structure are nearly coplanar, with an r.m.s. deviation for the tricyclic ring system of 0.0014 Å. The two 3-methyl-but-2-enyl side chains are in (+)-synclinal and (-)-anti-clinal conformations. Intra-molecular O-H⋯O and C-H⋯O inter-actions occur. The crystal structure is stabilized by inter-molecular O-H⋯O, C-H⋯O and C-H⋯π inter-actions.
منابع مشابه
3,5,3′-Trihydroxy-4′-methoxy-7-(3-methylbut-2-enyloxy)flavone
The title compound pteleifolosin C, C(21)H(20)O(7), was isolated from the petroleum ether-soluble fraction of an indigenous Chinese tree Melicope pteleifolia (Rutaceae). The dihedral angle between the benzene rings is 2.7 (2)°. Intra-molecular O-H⋯O hydrogen bonds occur. In the crystal, mol-ecules are linked by inter-molecular O-H-O hydrogen bonds.
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010